Those three are great for relaxing after a long day
FTL: Faster Than Light
Zachtronics games (TIS-100, Shenzhen I/O, Exapunks)
FEZ
Portal / Portal 2
XCOM
Deus Ex (Super old but quite good, I started it recently. I had best results in Proton selecting the software renderer in the first launch dialog instead of DX9)
Grand Theft Auto
Assassins Creed IV (I had trouble running this under Proton though, had to use Windows)
Planetside 2 is MMO but you can play singleplayer. Windows only unfortunately, but there's nothing else like it.
> Deus Ex (Super old but quite good, I started it recently. I had best results in Proton selecting the software renderer in the first launch dialog instead of DX9)
I recommend Deus Exe [0] for playing Deus Ex. And yes, it's still an awesome game.