That's funny you should say that, I initially started out using Fireworks when I started as an intern as a web developers. This was back in 2000, and designs were all table based, so Fireworks was great for splicing into the required segments.

I'd have to agree that Fireworks is probably better suited for most web design needs... It used to be real simple to switch between the 2 packages, guessing it is still the same...